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刘大欢
 
发布作者:  发布时间:2017-03-28 已读:
 
 
  

 

 


刘大欢,男,博士,见习教授,博士生导师。

 2006.12   北京化工大学 工学博士
 2007.4 至今 北京化工大学 讲师,副教授,见习教授,博士生导师

科研情况:
现主要从事面向清洁能源、环境应用的新型金属-有机骨架材料(Metal-organic frameworks, MOFs)分子设计与实验合成等方面的基础和应用基础研究。在J. Am. Chem. Soc., AIChE J., J. Mater. Chem. A, Chem. Commun.等期刊发表SCI收录论文86篇。

承担项目:
1. 芳香烃/脂肪烃分离功能导向的金属-有机骨架材料微环境构筑与性能调控研究,国家自然科学基金,项目负责人,2016-2019.
2. 金属—有机骨架材料用于有害大分子去除的理论与实验研究,国家自然科学基金,项目负责人,2013-2016。
3. 协同自组装形成的多微区胶束结构及以此设计中微孔金属-有机骨架材料的研究,国家自然科学基金,项目负责人,2010-2012
4. 新型金属―有机骨架材料应用于天然气净化的基础研究,中央高校基本科研业务费项目,项目负责人,2011—2012

担任的教学任务:
(1) “绿色化学导论”,研究生课程,主讲。
(2) “化工原理”,本科生课程,主讲。


发表论文:
62. T. Han, C. Li, X. Guo, H. Huang, D. Liu, C. Zhong. In-situ synthesis of SiO2@MOF composites for high-efficiency removal of aniline
from aqueous solution, App. Surf. Sci. 2016,DOI:10.1016/j.apsusc.2016.08.111.

61. Y. Ying, D. Liu, J. Ma, M. Tong, W. Zhang, H. Huang, Q. Yang, C. Zhong. A GO-assisted method for the preparation of ultrathin covalent organic framework membranes for gas separation, J. Mater. Chem. A, 2016, 4, 13444-13449.

60. W. Tang, J. Gu, H. Huang, D. Liu, C. Zhong. Metal-Organic Frameworks for Highly Efficient Adsorption of Dibenzothiophene from Liquid Fuels. AIChE J., 2016, DOI: 10.1002/aic.15384

59. Y. Huang, D. Liu, Z. Liu, C. Zhong. Synthesis of Zeolitic Imidazolate Framework Membrane Using Temperature-Switching Synthesis Strategy for Gas Separation, Ind. Eng. Chem. Res. 2016, 55, 7164-7170.

58. J. Ma, Y. Ying, X. Guo, H. Huang, D. Liu,C. Zhong, Fabrication of mixed-matrix membrane containing metal–organic framework composite with task specific ionic liquid for efficient CO2 separation, J. Mater. Chem. A, 2016, 4, 7281-7288.

57. X. Zhao, D. Liu, H. Huang, C. Zhong. Highly selective and sensitive metal-organic framework fluorescent probe for Cu2+ through rational design of binding sites. Micropor. Mesopor. Mater., 2016, 224, 149-154.

56.  Y. Huang, Y. Xiao, H. Huang, Z. Liu, D. Liu, Q. Yang and C. Zhong, Ionic liquid functionalized multi-walled carbon nanotubes/zeolitic imidazolate framework hybrid membranes for efficient H2/CO2 separation, Chem. Commun., 2015, 51, 17281-17284.

55. Y. Zhang, X. Zhao, H. Huang, Z. Li, D. Liu, C. Zhong, Selective removal of transition metal ions from aqueous solution by metal–organic frameworks, RSC Adv., 2015, 5, 72107–72112.

54. X. Zhao, X. Han, Z. Li, H. Huang, D. Liu, C. Zhong. Enhanced removal of iodide from water induced by a metal-incorporated porous metal–organic framework, Appl. Surf. Sci., 2015, 351, 760-764

53. D. Liu, T.-F. Liu, Y.-P. Chen, L. Zou, D. Feng, K. Wang, Q. Zhang, S. Yuan, C. Zhong and H.-C. Zhou, A Reversible Crystallinity-Preserving Phase Transition in Metal-Organic Frameworks: Discovery, Mechanistic Studies, and Potential Applications, J. Am. Chem. Soc., 2015, 137,7740–7746

52. Y. Ying, Y. Xiao, J. Ma, X. Guo, H. Huang, Q. Yang, D. Liu, C. Zhong, Recovery of acetone from aqueous solution by ZIF-7/PDMS mixed matrix membranes, RSC Adv., 2015, 5, 28394–28400.

51. K. Wang, H. Huang, W. Xue, D. Liu, X. Zhao, Y. Xiao, Z. Li, Q. Yang, L. Wang, C. Zhong, An ultrastable Zr metal-organic framework with a thiophene-type ligand containing methyl groups, CrystEngComm, DOi: 10.1039/c5ce00269a.
 
50. T. Han, Y. Xiao, M. Tong, H. Huang, D. Liu, L. Wang, C. Zhong, Synthesis of CNT@MIL-68(Al) composites with improved adsorption capacity for phenol in aqueous solution, Chem. Eng. J., 2015, 275, 134-141.

49. J. Ma, Y. Ying, Q.Yang, Y. Ban, H. Huang, X. Guo, Y. Xiao, D. Liu, Y. li, W. Yang and C. Zhong, Mixed-matrix membranes containing functionalized porous metal-organic polyhedrons for effective separation of CO2 /CH4 mixture,Chem. Commun., 2015, 51, 4249-4251.

48. Y. Xiao, T. Han, G. Xiao, Y. Ying, H. Huang, Q. Yang, D. Liu, and C. Zhong. Highly Selective Adsorption and Separation of Aniline/Phenol from Aqueous Solutions by Microporous MIL-53(Al): A Combined Experimental and Computational Study. Langmuir, 2014, 30,12229–12235.

47. L. Xie, D. Liu, H. Huang, Q. Yang, C. Zhong, Efficient capture of nitrobenzene from waste water using metal–organic frameworks, Chem. Eng. J., 2014, 246, 142-149.

46. X. Zhao, Dahuan Liu, H. Huang, W. Zhang, Q. Yang and C. Zhong. The stability and defluoridation performance of MOFs in fluoride solutions. Microporous & Mesoporous Mater., 2014, 185, 72-78

45. Y. Xiao, Q. Yang, Dahuan Liu and C. Zhong. Computational design of metal-organic frameworks for aniline recovery from aqueous solution. CrystEngComm, 2013, 15, 9588-9595. 

44. Q. Yang, Dahuan Liu, C. Zhong and J. Li, Development of Computational Methodologies for Metal-Organic Frameworks and Their Application in Gas Separations, Chem. Rev., 2013, 113, 8261–8323.

43. M. Tong, Dahuan Liu*, Q. Yang, S. Devautour-Vinot, G. Maurin and C. Zhong, Influence of the framework metal ions on the dye capture behavior of the MIL-100 (Fe, Cr) MOF type solids, J. Mater. Chem. A. 2013, 1, 8534-8537.

42. C. Zhang, Y. Xiao, Dahuan Liu*, Q. Yang, C. Zhong, A hybrid zeolitic imidazolate framework membrane by mixed-linker synthesis for efficient CO2 capture, Chem. Commun., 2013, 49, 600-602. 

41. W. Zhang, H. Huang, Dahuan Liu*, Q. Yang, Y. Xiao, Q. Ma, C. Zhong, A new metal–organic framework with high stability based on zirconium for sensing small molecules, Micropor. Mesopor. Mater., 2013, 171, 118-124. 

40. Dahuan Liu, W. Wang, J. Mi, C. Zhong, Q. Yang, D. Wu, Quantum sieving in metal-organic frameworks: a computational study, Ind. Eng. Chem. Res., 2012, 51, 434-442. 

39. D. Wu, C. Wang, B. Liu, Dahuan Liu*, Q. Yang and C. Zhong, Large-scale computational screening of metal-organic frameworks for CH4/H2 separation, AIChE J., 2012, 58, 2078-2084. 

38. D. Wu, Q. Yang, C. Zhong, Dahuan Liu*, H. Huang, W. Zhang, G. Maurin, Revealing the structure−property relationships of metal−organic frameworks for CO2 capture from flue gas, Langmuir, 2012, 28, 12094-12099.

37. F. Cao, C. Zhang, Y. Xiao, H. Huang, W. Zhang, Dahuan Liu*, C. Zhong, Q. Yang, Z. Yang, X. Lu, Helium recovery by a Cu-BTC metal−organic framework membrane, Ind. Eng. Chem. Res., 2012, 51, 11274-11278.

36. H. Huang, W. Zhang, Dahuan Liu*, C. Zhong, Understanding the effect of trace amount of water on CO2 capture in natural gas upgrading in metal-organic frameworks: a molecular simulation study, Ind. Eng. Chem. Res., 2012, 51, 10031-10038. 

35. W. Zhang, H. Huang, C. Zhong, Dahuan Liu*, Cooperative effect of temperature and linker functionality on CO2 capture from industrial gas mixtures in metal-organic frameworks: a combined experimental and molecular simulation study, Phys.Chem.Chem.Phys., 2012, 14, 2317-2325. 

34. W. Zhuang, D. Yuan, Dahuan Liu, C. Zhong, J.-R. Li, H.-C. Zhou, Robust metal−organic framework with an octatopic ligand for gas adsorption and separation: combined characterization by experiments and molecular simulation, Chem. Mater., 2012, 24, 18-25.

33. H. Zhang, H. Huang, C. Li, H. Meng, Y. Lu, C. Zhong, Dahuan Liu, Q. Yang, Adsorption behavior of metal−organic frameworks for thiophenic sulfur from diesel oil, Ind. Eng. Chem. Res., 2012, 51, 12449-12455. 

32. H. Huang, W. Zhang, Dahuan Liu*, B. Liu, G. Chen and C. Zhong, Effect of temperature on gas adsorption and separation in ZIF-8: a combined experimental and molecular simulation study, Chem. Eng. Sci., 2011, 66, 6297-6305. 

31. Q. Yang, L. Ma, C. Zhong, X. An and Dahuan Liu, Enhancement of CO2/N2 mixture separation using the thermodynamic stepped behavior of adsorption in metal−organic frameworks, J. Phys. Chem. C, 2011, 115, 2790-2797. 

30. W. Mu, Dahuan Liu and C. Zhong, A computational study of the effect of doping metals on CO2/CH4 separation in metal-organic frameworks, Micropor. Mesopor. Mater., 2011, 143, 66-72.

29. L. Zhao, Q. Yang, Q. Ma, C. Zhong, J. Mi and Dahuan Liu, A force field for dynamic Cu-BTC metal-organic framework, J. Mol. Model., 2011, 17, 227-234.

28. Dahuan Liu and C. Zhong, Understanding gas separation in metal-organic frameworks using computer modeling, J. Mater. Chem., 2010, 20, 10308-10318 (特邀 Feature Article).

27. Dahuan Liu and C. Zhong, Characterization of Lewis acid sites in metal-organic frameworks using density functional theory, J. Phys. Chem. Lett., 2010, 1, 97-101.

26. Q. Xu, Dahuan Liu, Q. Yang, C. Zhong and J. Mi, Li-modified metal-organic frameworks for CO2/CH4 separation: a route to achieving high adsorption selectivity, J. Mater. Chem., 2010, 20, 706-714. 

25. D. Wu, Q. Xu, Dahuan Liu and C. Zhong, Exceptional CO2 capture capability and molecular-level segregation in a Li-modified metal-organic framework, J. Phys. Chem. C, 2010, 114, 16611-16617. 

24. W. Mu, Dahuan Liu, Q. Yang and C. Zhong, Computational study of the effect of organic linkers on natural gas upgrading in metal-organic frameworks, Micropor. Mesopor. Mater. 2010, 130, 76-82.

23. Y. Liu, Dahuan Liu, Q. Yang, C. Zhong and J. Mi, A comparative study of separation performance of COFs and MOFs for CH4/CO2/H2 mixtures, Ind. Eng. Chem. Res., 2010, 49, 2902-2906.

22. Q. Ye, S. Yan, Dahuan Liu*, Q. Yang and C. Zhong, Methane adsorption in several series of newly-synthesized metal-organic frameworks: a molecular simulation study, Mol. Simulat., 2010, 36, 682-692. 

21. Q. Ma, Q. Yang, C. Zhong, J. Mi and Dahuan Liu, Studies of capillary phase transitions of methane in metal-organic frameworks by gauge cell Monte Carlo simulation, Langmuir, 2010, 26, 5160-5166. 

20. Dahuan Liu, C. Zheng, Q. Yang and C. Zhong, Understanding the adsorption and diffusion of carbon dioxide in zeolitic imidazolate frameworks: A molecular simulation study, J. Phys. Chem. C, 2009, 113, 5004-5009.

19. Dahuan Liu, Q. Yang and C. Zhong, Adsorption of methane in heterometallic metal-organic frameworks with anions: a molecular simulation study, Mol. Simulat., 2009, 35, 213-219.

18. J. Xin, Dahuan Liu and C. Zhong, Morphology and structure control of multicompartment micelles from triblock copolymer blends, J. Phys. Chem. B, 2009, 113, 9364-9372. 

17. C. Zheng, Dahuan Liu, Q. Yang, C. Zhong, and J. Mi, A computational study of the influences of framework charges on CO2 uptake in metal-organic frameworks, Ind. Eng. Chem. Res. 2009, 48, 10479-10484. 

16. Q. Xu, Dahuan Liu, Q. Yang and C. Zhong, Molecular simulation study of the quantum effects of hydrogen adsorption in metal-organic frameworks: influences of pore size and temperature, Mol. Simulat., 2009, 35, 748-754.

15. Dahuan Liu and C. Zhong, Multicompartment micelles formed from star-dendritic triblock copolymers in selective solvents: A dissipative particle dynamics study, Polymer, 2008, 49, 1407-1413. 

14. H. Qi, Dahuan Liu and C. Zhong, Cooperative aggregation of amphiphilic comblike copolymer/linear homopolymer blends in selective solvents: a density functional theory study, J. Phys. Chem. B, 2008, 112, 16409-16414. 

13. J. Xin, Dahuan Liu and C. Zhong, Multicompartment micelles from star and linear triblock copolymer blends, J. Phys. Chem. B, 2007, 111, 13675-13682. 

12. J. Xia, Dahuan Liu* and C. Zhong, Multicompartment micelles and vesicles from π-shaped ABC block copolymers: A dissipative particle dynamics study, Phys.Chem.Chem.Phys., 2007, 9, 5267-5273. 

11. C. Zhong, Dahuan Liu. Understanding Multicompartment Micelles Using Dissipative Particle Dynamics Simulation, Macromol. Theor. Simul., 2007, 16, 141-157. (特邀Feature Article,封面论文)

10. Dahuan Liu, C. Zhong. Novel Two-compartment Micelles Formed by Self-Assembly of Linear Pentablock Copolymers in Selective Solvent, Macromol. Rapid. Commun., 2007, 28, 292-297. 

9. Dahuan Liu, C. Zhong. Cooperative Self-Assembly of Nanoparticle Mixtures in Lamellar Diblock Copolymers: A Dissipative Particle Dynamics Study, Macromol. Rapid. Commun. 2006, 27, 458-462. 

8. Dahuan Liu, C. Zhong. Dissipative Particle Dynamics Simulation of Microphase Separation and Properties of Linear-Dendritic Diblock Copolymer Melts under Steady Shear Flow, Macromol. Rapid. Commun. 2005, 26, 1960-1964. 

7. Dahuan Liu, C. Zhong. Modeling of the Heat Capacity of Polymers with the Variable Connectivity Index, Polym. J., 2002, 34, 954-961. 

6. 童敏曼,赵旭东,谢丽婷,刘大欢*,阳庆元,仲崇立,金属-有机骨架材料用于废水处理,化学进展,2012, 24, 1646-1655.(特约稿)

5. 张秀芳,安晓辉,刘大欢*,阳庆元,杨祝红,仲崇立,陆小华,离子交换对usf-ZMOF二氧化碳吸附能力影响的研究,化学学报,2011,69,84-88.

4. 向辉,刘大欢*,阳庆元,密建国,仲崇立,骨架柔性对短链烷烃分子在金属-有机骨架材料中扩散的影响,物理学报,2011,60,093602. 

3. 安晓辉,刘大欢*,仲崇立,二氧化碳在金属-有机骨架材料中吸附的阶梯现象,物理化学学报,2011,27,553-558. 

2. 穆韡,刘大欢*,阳庆元,仲崇立,金属-有机骨架材料中气体扩散速率的分子模拟,物理化学学报,2010,26,1657-1663. 

1. 阳庆元, 刘大欢, 仲崇立,金属-有机骨架材料的计算化学研究,化工学报,2009,60,805-819(综述).

 

 
 
 
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